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Periodic acid : ウィキペディア英語版
Periodic acid

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Periodic acid (pronounced per-iodic , rather than as in ''periodic table'') is the highest oxoacid of iodine, in which the iodine exists in oxidation state VII. Like all periodates it can exist in two forms: orthoperiodic acid, with the chemical formula H5IO6 and metaperiodic acid, which has the formula HIO4.
Periodic acid was discovered by Heinrich Gustav Magnus and C. F. Ammermüller in 1833.
==Synthesis==
Modern industrial scale production involves the electrochemical oxidation of iodic acid, on a PbO2 anode, with the following standard electrode potential:
:H5IO6 + H+ + 2 e → IO3 + 3 H2O 1.6
Orthoperiodic acid can be dehydrated to give metaperiodic acid by heating to 100 °C
:HIO4 + 2H2O H5IO6
Further heating to around 150 °C gives Iodine pentoxide (I2O5) rather than the expected anhydride ''diiodine heptoxide'' (I2O7). Metaperiodic acid can also be prepared by from various orthoperiodates by treatment with dilute nitric acid.
:H5IO6 → HIO4 + 2 H2O

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